Trivalent chromium is the dominant form in the environment (soil, in many fresh vegetables, fruits, meat, grains) whilst hexavalent chromium is soluble in water and it can migrate in the direction of the groundwater, under highly...
moreTrivalent chromium is the dominant form in the environment (soil, in many fresh vegetables, fruits, meat, grains) whilst hexavalent chromium is soluble in water and it can migrate in the direction of the groundwater, under highly oxidizing conditions and pH values over 7.
Since September 2007, the University of Athens has started sampling groundwater and surface water and from several sites of the Asopos valley, whereindustrial activities are well known during the last 30 years, in order to investigate the
Cr6+level in drinking water. Concentrations over the maximum level of total Cr in drinking water (50 ppb, according to the EC Regulation) were found in the urban water supply of Oropos (up to 80 ppb Cr6+), Oinofyta (up to 53 ppb) and Nea Ekali (62 ppb Cr6+). High concentrations of Cr6+, ranging from 5 to 33 Cr6+, were also found in the water of the town of Thiva. With the exception of the As, the Pb, Ni, Cu, Cd, Hg, Sb contents in 28 groundwater samples, that are representative of all water types, analyzed for Cr- Cr6+, were lower than permeable limits. High As content (up to 34 ppb As) were detected in central water system of Dilesi.
The contamination of groundwater by Cr6+ that was found in the majority of water drillings in the Asopos valley is related to the widespread industrial activity and the usage of hexavalent chromium in various processes. In order to reduce the concentration of total chromium below the EC maximum contaminant level (50 ppb) and the proposed level for Cr6+ by other countries, remediation strategies should focus on the reduction of Cr6+ to the insoluble trivalent forms, that are relatively stable and non-toxic.
Recently, a removal process of hexavalent chromium, using scrap iron filings, has been proposed: Cr6+ + Fe0 → Cr3+ + Fe3+ Trivalent chromium and total iron can be removed from the aqueous solution by precipitation with alkaline solutions. This is a low-cost method for the reduction of Cr6+. Hexavalent chromium in groundwater of the Asopos valley is related to the anthropogenic activities in that region (from the discharges of Cr-bearing wastes), rather than ultramafic ophiolitic rocks, as is exemplified by a strong positive correlation between Cr6+ and Mg (r = 0.88) only in the latter.
According to the literature and our experimental work, the Cr6+ in the above measured concentrations, can be removed from drinking water by using an activated carbon filter.
Our preliminary results may indicate that all Water Protection Agencies, in addition to those elements listed currently, must require information about the hexavelent chromium as well, in particular in the bottled water. Also, monitoring may help local
municipalities in the Asopos valley to determine where certain contaminants occur and whether the contaminants need to be regulated.
KEYWORDS: Region of Attika, Region of Sterea Hellas, industrial pollution.
Πρόκειται για την πρώτη ερευνητική εργασία που παρουσιάστηκε σε διεθνές επιστημονικό συνέδριο σχετικά με το πρόβλημα της ρύπανσης με εξασθενές χρώμιο στην περιοχή του Ασωπού ποταμου.
Έγινε γεωχημική μελέτη της ρύπανσης του υδροφόρου ορίζοντα στην περιοχή του Ασωπού ποταμού από βιομηχανικά απόβλητα με εξασθενές χρώμιο και άλλα τοξικά μέταλλα. Τα πειράματά μας έδειξαν ότι το εξασθενές χρώμιο μπορεί να απομακρυνθεί από το πόσιμο νερό με χρήση φίλτρου με ενεργό άνθρακα.